FORMATION PROCESS OF A FLUID TANGLED LAMINATED BLANKET

专利摘要:
laminated sheets interwoven by fluid, with hollow projections and a process and equipment for their manufacture. The present invention is directed to a fluid-entangled laminate web and the process and equipment for forming it, as well as the end uses of the fluid-entangled laminate web. the laminated mat includes a backing layer and a non-woven projection mat having a plurality of projections, which are preferably hollow. as a result of the fluid entanglement process, the entanglement fluid is directed through the support layer and into the projection mat, which is situated on a forming surface. the force of the entanglement fluid causes the two layers to bond together and the fluid causes part of the fibers in the projection mat to be forced into the openings present in the forming surface, forming the hollow projections. The resulting laminate has numerous uses, including but not limited to wet and dry cleaning materials, as well as the incorporation of various parts of absorbent personal care articles and use in packaging, especially food packaging, where fluid control is essential. a problem.
公开号:BR112015009434B1
申请号:R112015009434-1
申请日:2013-10-30
公开日:2022-01-04
发明作者:Niall Finn；Scott S.C. Kirby；Andy R. Butler
申请人:Kimberly-Clark Worldwide, Inc；
IPC主号:

专利说明:

HISTORY OF THE INVENTION
[1] Non-woven fibrous materials are being widely used in a variety of applications, including but not limited to absorbent structures and cleaning products, many of which are disposable. In particular, such materials are commonly used in absorbent personal care articles such as diapers, diaper pants, sweatpants, feminine hygiene products, adult incontinence products, bandages and cleaning products such as baby and adult baby wipes. They are also commonly used in cleaning products such as disposable wet and dry wipes, which can be treated with cleaning compounds and other compounds that are designed to be used by hand or in conjunction with cleaning devices such as scourers. However, a new application is as a beauty accessory, such as wipes and sponges for cleaning and makeup removal.
[2] In many of these applications, three-dimensionality and greater surface area are desirable attributes. This is particularly true for materials in contact with the body for the aforementioned absorbent personal care articles and cleaning products. One of the main functions of absorbent personal care articles is to absorb and retain bodily exudates such as blood, menstrual flow, urine and bowel movements. By providing fibrous nonwovens with hollow projections, several attributes can be achieved at the same time. First, by providing projections, the laminate in general can be made to have a greater degree of thickness while minimizing the amount of material used. The increased thickness of the material serves to improve the separation of the wearer's skin from the absorbent core, therefore improving the possibility of drier skin. By providing projections, landing areas are created between the projections which can temporarily distance exudates from the high points of the projections while exudates are being absorbed, thus reducing skin contact and providing better skin benefits. Second, by providing such projections, the spread of exudates in the finished product can be reduced, thus exposing the skin less to contamination. Third, by providing projections, the cavities themselves can serve as fluid reservoirs to temporarily store body exudates and later allow the exudates to move vertically into underlying layers of the overall product. Fourth, by reducing overall skin contact, fibrous non-woven laminate with these projections can provide a smoother feel to the skin in contact, thus improving the tactile aesthetics of the layer and the product in general. Fifth, when these materials are used as body contact lining materials for products such as diapers, diaper pants, training pants, adult incontinence products and feminine hygiene products, the lining material also plays a role. to act as a cleaning aid when the product is removed. This is especially the case with menstrual flow and lower viscosity bowel movements, which are commonly found in conjunction with such products. Here again, such materials can provide an additional benefit from a cleanliness and containment perspective.
[3] In the context of cleaning products, again, projections can provide a greater total surface area for collection and containment of material removed from the surface to be cleaned. In addition, cleaning compounds and other compounds can be loaded into the hollow projections to store and then, upon use, release this cleaning compound and other compounds onto the surface to be cleaned.
[4] Other attempts have been made to provide non-woven fibrous mats that provide the aforementioned attributes and fulfill the aforementioned tasks. Such an approach has been the use of various types of embossing to create three-dimensionality. This works to an extent, however high basis weights are required to create a structure with significant topography. Furthermore, it is inherent in the embossing process that the initial thickness is lost due to the fact that embossing is, by its nature, a crushing and bonding process. In addition, to “place” embossing on a non-woven fabric, the densified sections are often fused together to create the weld points that are normally fluid impermeable. Thus, a part of the area is lost for the fluid to transit through the material. In addition, “priming” the fabric can cause the material to stiffen and become hard to the touch.
[5] Another approach to providing the aforementioned attributes has been to form fibrous mats on three-dimensional forming surfaces. The resulting structures typically have little strength at low basis weight (assuming soft fibers with desirable aesthetic attributes are used) and topography is significantly degraded when wound on a roll and subjected to subsequent converting processes. This is partially resolved in the three-dimensional forming process, allowing the three-dimensional shape to be filled with fiber. However, this often comes at a higher cost due to the use of more material and at the expense of softness, as well as the fact that the resulting material becomes aesthetically unappealing for certain applications.
[6] Another approach to providing the aforementioned attributes was the opening of a fibrous blanket. Depending on the process, this can generate a flat two-dimensional mat or a mat with some three-dimensionality, where the displaced fiber is pushed out of the plane of the original mat. Typically, the extent of three-dimensionality is limited, and under sufficient load, the displaced fiber can be pushed back from its initial position, resulting in at least partial closure of the opening. Drilling processes that attempt to “adjust” the displaced fiber out of the plane of the original mat are also prone to degradation of the softness of the original mat. Another problem with perforated materials is that when they are incorporated into final products, since this is done using adhesives, due to their open structure often the adhesives will penetrate through the perforations in the nonwoven from the underside to the bottom. exposed surface from above, thus creating unwanted problems such as glue build-up in the converting process or the creation of unwanted bonds between layers in the finished product.
[7] As a result, there is still a need for both a material and a process and equipment that provide three-dimensional characteristics that meet the aforementioned needs. SUMMARY OF THE INVENTION
[8] The present invention is directed to fluid-woven laminates having a fibrous non-woven layer having projections that are preferably hollow and extending from a surface of the laminate, as well as the process and equipment for manufacturing such laminates and their incorporation into final products.
[9] The fluid-entangled laminated mat in accordance with the present invention, while capable of having other layers incorporated therein, includes a backing layer having a first and second surface and a thickness, and a projection mat not woven fabric, which comprises a plurality of fibers and has opposing inner and outer surfaces and a thickness. The second surface of the backing layer abuts the inner surface of the projection mat and a first plurality of the fibers in the projection mat form a plurality of projections extending outward from the outer surface of the projection mat. A second plurality of the fibers in the projection batt are interwoven with the backing layer to form the fluid-entangled laminate batt.
[10] The portion of the projection mat with the laminate and its projections provides a wide variety of attributes that make it suitable for numerous end uses. In preferred embodiments, all or at least a portion of the projections define hollow interiors.
[11] The backing layer can be made from a variety of materials, including a continuous fiber mat such as spunbond material, or it can be made from staple staple fiber mats. The projection mat may also be made from batts of continuous or discontinuous fibers, although it is desirable that the projection batt has less fiber bonding or fiber entanglement than the backing layer to facilitate the formation of the projections.
[12] The support layer and projection mat can be made of various basis weights depending on the specific end-use application. A unique attribute of the laminate and process is the ability to make laminates at what are considered low basis weights for applications including, but not limited to, absorbent personal care products and food packaging components. For example, the fluid-entangled laminate webs of the present invention may have overall basis weights of between about 25 to 100 grams per square meter (gsm) and the backing layer may have a basis weight of between about 5 and 40 grams. per square meter meters while the projection blanket can have a basis weight between about 10 and 60 grams per square meter. Such basis weight ranges are possible due to the way the laminate is molded and the use of two different layers with different functions regarding the forming process. As a result, laminates can be made in commercial environments that until now were not considered possible due to the inability to process the individual mats and form the desired projections.
[13] The laminated blanket of the present invention can be incorporated into absorbent articles for a variety of uses, including, but not limited to, diapers, diaper pants, training diapers, incontinence devices, feminine hygiene products, bandages and handkerchiefs. Generally, such products will include a body side liner or skin contacting material, a garment contacting material called a backsheet, and an absorbent core disposed between the bodyside liner and the backsheet. In that regard, such absorbent articles may have at least one layer that is made, at least in part, of the fluid-entangled laminated mat of the present invention, including, but not limited to, one of the outer surfaces of the absorbent article. If the outer surface is the body-contacting surface, the fluid-entangled laminate mat can be used alone or in combination with other layers of absorbent material. In addition, the fluid-entangled laminate web may include hydrogel, also known as a superabsorbent material, preferably in the backing layer portion of the laminate. If the laminated mat is used as an outer surface on the garment side of the absorbent article, it may be desirable to attach a liquid impermeable layer, such as a film layer, to the first surface or outer surface of the backing layer and the position of this impermeable layer to liquids to the inside of the absorbent article so that the projection mat is on the outside of the absorbent article. This same type of configuration can also be used in food packaging to absorb fluids from the contents of the package.
[14] In addition, it is also common for absorbent articles to have an optional layer, commonly called a peak or transfer layer, disposed between the body side liner and the absorbent core. When such products are in the form of, for example, diapers and incontinence devices for adults, they may also include what are termed "ears" located in the front and/or back waist regions on the sides of the products. These ears are used to fix the product on the user's torso, usually in conjunction with adhesive and/or mechanical hook and loop fastening systems. In certain applications, the fastening systems are connected to the distal ends of the ears and connected to what is called a “front patch” or “tape landing zone”, located at the front of the product's waist. The fluid woven laminate web of the present invention may be used for all or part of any one or more of these components and products.
[15] When such absorbent articles are in the form of, for example, a diaper-pants training diaper or other product that is intended to be pulled on and worn like underwear, such products will generally include what are termed "side panels". , connecting the front and back waist regions of the product. Such side panels may include both elastic and non-elastic portions and the fluid-entangled laminate batts of the present invention may be used with all or part of such side panels.
[16] Accordingly, such absorbent articles may have at least one layer, in whole or in part, comprising the fluid-entangled laminate mat of the present invention.
[17] Also described herein are numerous configurations of equipment and processes for forming fluid-entangled laminated mat in accordance with the present invention. Such a method includes the steps of providing a projection forming surface method which defines a plurality of forming holes in such a surface, with the forming holes spaced from one another and with landing areas therebetween. The projection forming surface is capable of movement in one machine direction at the speed of the projection forming surface. A projection fluid entanglement device is also provided, and has a plurality of projection fluid jets capable of emitting a plurality of pressurized streams of projection fluid towards the projection forming surface.
[18] Next, a backing layer with opposing first and second surfaces and a non-woven projection mat having a plurality of fibers and opposing inner and outer surfaces are provided. The projection mat is fed into the projection forming surface with the outer surface of the projection mat positioned adjacent to the projection forming surface. The second surface of the support layer is fed onto the inner surface of the projection mat. A plurality of pressurized projecting fluid streams of entanglement fluid from several jets of projecting fluid are directed from the first surface of the support layer towards the projection forming surface to create a) a first plurality of fibers in the projection mat in the vicinity of the forming holes in the projection forming surface to be directed into the forming holes and forming a plurality of projections projecting outward from the outer surface of the projection mat, and b) a second plurality of fibers in the projection mat are interwoven with the backing layer to form a laminated mat. This entanglement may be the result of the fibers of the projection mat intertwining with the backing layer or, when the backing layer is also a fibrous structure, the fibers of the backing layer intertwining with the fibers of the projection mat or a combination of the two described entanglement processes. Furthermore, the first and second plurality of fibers in the projection mat can be the same amount of fibers, especially when the projections are closely spaced as the same fibers, if it is a sufficient length, both can form the projections and tangle with each other. the support layer.
[19] After formation of projections on the projection mat and coupling of the projection mat with the backing layer to form the laminate mat, the laminate mat is removed from the projection-forming surface. In certain embodiments of the process and equipment, it is desirable that the direction of the plurality of fluid flows causes the formation of projections which are hollow.
[20] In a preferred embodiment, the projection forming surface comprises a texturing cylinder, although it is also possible to shape the forming surface from a belt system or a belt and cable system. In certain embodiments it is desirable that the landing areas of the projection forming surface are not fluid permeable, in other situations they may be permeable, especially when the forming surface is a porous forming wire. If desired, the forming surface may be shaped with raised areas, in addition to the holes, to form depressions and/or openings in the landing areas of the fluid-woven laminated mat in accordance with the present invention.
[21] In alternative executions of the equipment, the spray mat and/or backing layer can be introduced into the spray forming process at the same speed that the spray forming surface is moving or at a faster or faster speed. slow. In certain embodiments of the process, it is desirable for the projection mat to be introduced onto the projection-forming surface at a rate greater than the rate of introduction of the support layer onto the projection mat. In other situations, it may be desirable to introduce both the projection mat and backing layer onto the projection-forming surface at a rate that is greater than the speed of the projection-forming surface. The introduction of excess material into the process has been found to provide an additional fibrous structure within the projection mat for forming the projections. The rate at which material is introduced into the process is called the overfeed rate. It has been found that particularly well-formed projections can be made when the overfeed ratio is between about 10 and 50 percent, meaning that the speed at which material is introduced into the process and equipment is between about 10 and 50 percent. percent faster than the projection forming surface speed. This is particularly advantageous with regard to overfeeding the spray blanket in the process and equipment.
[22] In an alternative form of process and equipment, a pre-rolling step is provided prior to the projection forming step. In this embodiment, the equipment and process are provided with a lamination forming surface that is fluid permeable. The roll forming surface is capable of moving in the machine direction at a roll forming surface speed. As with another embodiment of process and equipment, a projection forming surface is provided which defines a plurality of forming holes in such a surface, with the forming holes spaced from one another and with landing areas therebetween. The projection forming surface is capable of moving in the machine direction at the speed of the projection forming surface. The equipment and process also includes a fluid entanglement lamination device having a plurality of jets of lamination fluid capable of emitting a plurality of pressurized streams of lamination fluid towards the lamination forming surface, and a projection device by entanglement with fluid having a plurality of jets of projecting fluid, capable of emitting a plurality of projecting fluid streams of an entanglement fluid from the jets of projecting fluid towards the projection-forming surface.
[23] As with other method and equipment, a backing layer with opposing first and second surfaces and a projection mat having a plurality of fibers and opposing inner and outer surfaces are provided. The support layer and projection mat are introduced into the lamination-forming surface, at which point, a plurality of pressurized lamination fluid streams of entanglement fluid are directed from a plurality of lamination fluid jets within the lamination fluid. support layer and projection mat, to cause at least a portion of the fibers of the projection mat to entangle with the backing layer to form a laminated mat.
[24] After the laminated mat is formed, it's projection is fed into the projection-forming surface with the outer surface of the projection mat positioned adjacent to the projection-forming surface. Next, a plurality of pressurized projecting fluid streams of the entanglement fluid from several jets of projecting fluid are directed on the laminate mat toward the first surface of the support layer toward the projection-forming surface to create the first plurality of fibers in the projection mat in the vicinity of forming holes in the projection forming surface to be directed into the forming holes and form a plurality of projections projecting outward from the outer surface of the projection mat. The formed fluid-entangled laminated mat is removed from the projection-forming surface.
[25] In the process that employs a lamination step prior to the projection forming step, lamination may occur with the backing layer being the layer that is in direct contact with the lamination forming surface or with the projection mat being in direct contact with the rolling forming surface. When the backing layer is introduced to the lamination-forming surface, its first surface will be adjacent to the lamination-forming surface, thus forming the inner surface of the projection mat, which is then introduced to the second surface of the backing layer. As a result, a plurality of pressurized lamination fluid streams of the entanglement fluid emanating from the pressurized lamination fluid jets are directed from the outer surface of the projection blanket towards the lamination forming surface to cause at least one part of the fibers of the projection mat entangle with the backing layer to form a laminate mat.
[26] As with the first process, the projection-forming surface may comprise a texturing cylinder and, in certain applications, it is desirable that the landing areas of the projection-forming surface are not fluid permeable with respect to the projection fluid. entanglement being used. It is also desirable that a plurality of pressurized projection fluid streams cause projections to form which are hollow. In addition, the projection mat can be introduced onto the backing layer at a rate greater than the rate at which the backing layer is introduced onto the lamination-forming surface. Alternatively, the projection mat and backing layer may be introduced onto the roll forming surface at a rate greater than the speed of the roll forming surface. The overfeed ratio for material being introduced into the roll forming part of the process can be between 10 and 50 percent. Once the laminated mat is molded, it can be introduced onto the projection-forming surface at a speed greater than the speed of the projection-forming surface.
[27] In some applications, it may be desirable for the projections to have additional stiffness and abrasion resistance, such as when the laminate mat is used as a cleaning pad or where the projections and the overall laminate will encounter more vertical compressive forces. In such situations, it may be desirable to mold the projection mat with fibers that are capable of bonding or being bonded together, either through the use of bicomponent fibers. Alternatively or in addition to this, chemical bonding, such as through the use of acrylic resins, can be used to bond the fibers together. In such situations, the laminated mat may undergo additional processing, such as a bonding step where the newly formed laminate is subjected to a heating or other non-compressive bonding process, which fuses all or part of the fibers in the projections. and, if desired, the surrounding areas together to give the laminate more structural rigidity.
[28] These and other embodiments of the present invention are presented in more detail below. BRIEF DESCRIPTION OF THE DRAWINGS
[29] A complete and informative publication of the present invention, including the best methods, is described in more detail in the remainder of the specification, which includes references to the accompanying figures, in which:
[30] Figure 1 is a perspective view of an embodiment of a fluid-entangled laminated mat in accordance with the present invention.
[31] Figure 2 is a cross-section of the material shown in Figure 1, taken along line 2-2 of Figure 1.
[32] Figure 2A is a cross-sectional view of the material according to the present invention, taken along line 2-2 of Figure 1, showing possible directions of fiber movement within laminates due to the fluid entanglement process. according to the present invention.
[33] Figure 3 is a schematic side view of a process and equipment in accordance with the present invention for forming a fluid woven laminate web in accordance with the present invention.
[34] Figure 3A is an exploded view of a representative part of a first projection forming surface in accordance with the present invention.
[35] Figure 4 is a schematic side view of an alternative process and equipment in accordance with the present invention for forming a fluid woven laminate web in accordance with the present invention.
[36] Figure 4A is a schematic side view of an alternative process and equipment of the present invention for forming a fluid woven laminate web in accordance with the present invention, which is an adaptation of the equipment and process shown in Figure 4, as well as in Figures 5 and 7 below.
[37] Figure 5 is a schematic side view of an alternative process and equipment in accordance with the present invention for forming a fluid woven laminate web in accordance with the present invention.
[38] Figure 6 is a schematic side view of an alternative process and equipment in accordance with the present invention for forming a fluid woven laminate web in accordance with the present invention.
[39] Figure 7 is a schematic side view of an alternative process and equipment in accordance with the present invention for forming a fluid woven laminate web in accordance with the present invention.
[40] Figure 8 is a photomicrograph at a 45 degree angle showing a fluid-entangled laminated mat in accordance with the present invention.
[41] Figures 9 and 9A are microphotographs showing a fluid-entangled laminated mat in accordance with the present invention.
[42] Figure 10 is a perspective sectional view of an absorbent article in which, in accordance with the present invention, a fluid-entangled laminate web may be used.
[43] Figure 11 is a graph illustrating the fabric thickness as a function of the overfeed ratio of the projection mat in the forming process.
[44] Figure 12 is a graph showing the fabric stretch at a load of 10N as a function of the overfeed ratio of the projection mat for the process of forming both the laminates according to the present invention and the matting mats. projection not supported.
[45] Figure 13 is a graph depicting the load in Newtons per 50 millimeters width as a function of percent span comparing both laminates in accordance with the present invention and unsupported projection mat.
[46] Figure 14 is a graph depicting the load in Newtons per 50 mm width as a function of percent strain for a series of laminates in accordance with the present invention while varying the overfeed ratio.
[47] Figure 15 is a graph plotting the load in Newtons per 50 mm width as a function of percent span for a series of 45 gsm spray blankets while varying the overfeed ratio.
[48] Figure 16 is a top view photograph of a sample designated as code 3-6 in Table 1 of the specification.
[49] Figure 16A is a photo of a sample designated as code 3-6 in Table 1 of the specification taken at a 45 degree angle.
[50] Figure 17 is a top view photograph of a sample designated as code 5-3 in Table 1 of the specification.
[51] Figure 17A is a photo of a sample designated as code 5-3 in Table 1 of the specification taken at a 45 degree angle.
[52] Figure 18 is a photograph showing the juxtaposition of a portion of a fabric with and without a backing layer supporting the projection mat, having been processed simultaneously on the same machine.
[53] The repeated use of reference characters in this specification and in the drawings presented is intended to represent the same or analogous features or elements of the present invention. DETAILED DESCRIPTION OF REPRESENTATIVE FORMS Definitions
[54] As used herein the term "woven or non-woven batt" refers to a batt with a structure of individual fibers filaments or segments that are interposed (collectively referred to as "fibers" for simplicity), that are interwoven, but not identifiable as a knitted fabric. Non-woven fabrics or batts have been formed from many processes such as melting and spraying processes, continuous bonding processes after extrusion, bonded carded batting processes, etc.
[55] As used herein, the term "blown blown blanket" generally refers to a non-woven web that is formed by a process whereby a molten thermoplastic material is extruded through a plurality of matrix capillaries, usually circular, such as fibers fused into high-velocity converging streams of gas (e.g. air) that attenuate the fibers of the molten thermoplastic material to reduce their diameter, which can be the diameter of a microfiber. Thereafter, the fused and blown fibers are carried by the high-velocity gas flow and are deposited on a collection surface to form a web of randomly scattered fused and blown fibers. Such a process is disclosed, for example, in US Patent No. 3,849,241 to Butin, et al., which is incorporated herein in its entirety by reference for all purposes. Generally speaking, the cast and blown fibers can be microfibers that are substantially continuous or discontinuous, generally less than 10 microns in diameter, and generally tacky when deposited on a collection surface.
[56] As used herein, the term "continuous bonding mat after extrusion" generally refers to a mat containing continuous fibers of substantially small diameter. The fibers are formed by extrusion of a molten thermoplastic material from a plurality of fine, generally circular capillaries with the diameter of the extruded fibers then being rapidly reduced as through, for example, pull extrusion and/or other well-known mechanisms of continuous bonding after extrusion. The production of continuous bond mats after extrusion is described and illustrated, for example, in US Patent No. 4,340,563 to Appel, et al., Patent No. 3,692,618 to Dorschner, et al., Patent No. No. 3,802,817 to Matsuki, et.al., Patent No. 3,338,992 to Kinney, Patent No. 3,341,394 to Kinney, Patent No. 3,502,763 to Hartman, Patent No. 3,502,538 to Levy, Patent No. 3,542,615 to Dobo, et al., and Patent No. 5,382,400 to Pike, et al., which are incorporated in their entirety herein by reference for all purposes. Continuous bonding fibers after extrusion are generally non-sticky when deposited on a collecting surface. Continuously bonded fibers after extrusion can sometimes have diameters less than about 40 microns and often between about 5 to about 20 microns. To provide additional integrity to the batts, the formed batts can be subjected to additional fiber bonding techniques if desired. See, for example, US Patent No. 3,855,046 to Hansen, et al., which is incorporated herein in its entirety by reference for all purposes.
[57] As used herein, the term "carded batt" generally refers to a batt containing longitudinally bonded natural or synthetic fibers, typically having fiber lengths of less than 100 millimeters. Staple fiber bales are subjected to the splitting process to separate the fibers, which are then sent to a carding process that separates and combs the fibers to align them in the machine direction after being deposited onto a moving wire for further processing. . These mats are usually subjected to some type of bonding process, such as thermal bonding using heat and/or pressure. In addition to, or instead of, the fibers may be subjected to adhesive processes to bond the fibers together, such as through the use of powdered adhesives. Still further, the carded batt may be subjected to fluid entanglement, such as wet tangling, to further intertwine the fibers and thereby improve the integrity of the carded batt. Carded batts, due to the alignment of the fibers in the machine direction, once bonded will generally have more force in the machine direction than in the cross-machine direction.
[58] As used herein, the term "fluid entanglement" and generally "fluid entanglement" refers to a forming process to further increase the degree of entanglement of fibers within a given non-entangled fibrous mat or between mats. non-woven fibers and other materials, so as to make it difficult for individual fibers and/or layers to separate as a result of entanglement. Generally this is achieved by supporting the non-woven fibrous mat on some form of forming or carrying surface, which has at least some degree of permeability to the pressurized fluid being applied. A stream of pressurized fluid (usually multiple streams) is then directed against the surface of the non-woven mat that faces the supported surface of the mat. The pressurized fluid touches the fiber and forces parts of the fibers in the direction of fluid flow, thus displacing all or part of several fibers towards the supported surface of the blanket. The result is additional entanglement of the fibers in what might be called the blanket's Z direction (its thickness) relative to its flattest dimension, its X-Y plane. When two or more separate mats or other layers are placed adjacent to each other on the forming/carrying surface and subjected to pressurized fluid, generally the desired result is that some of the fibers from at least one of the mats are forced into the mat or layer. adjacent, causing the entanglement of fibers between the interfaces of the two surfaces, so as to result in the binding or joining of the mats/layers due to the greater entanglement of the fibers. The degree of binding or entanglement will depend on a number of factors including, but not limited to, the type of fibers being used, the lengths of fibers, the degree of pre-bonding or entanglement of the mat or mats before being subjected to the entanglement process. with fluid, the type of fluid to be used (liquids such as water, steam or gases such as air), fluid pressure, number of fluid flows, process speed, fluid residence time and porosity of the mat or mats/other layers and the forming/carrying surface. One of the most common fluid entanglement processes is cited as hydroentanglement, which is a process well known to those of ordinary skill in the area of non-woven fabrics. Examples of fluid entanglement processes can be found in US Patent No. 4,939,016 to Radwanski et al., US Patent No. 3,485,706 to Evans, and US Patent Nos. 4,970,104 and 4,959 .531 to Radwanski, which are incorporated herein in their entirety by reference for all purposes. DETAILED DESCRIPTION OF THE INVENTION
[59] Detailed references will be made to various embodiments of the invention, with one or more examples described below. Each example is provided for the purpose of explaining the invention, and not as a limitation of the invention. Indeed, it will be apparent to those skilled in the art that various modifications and variations may be made to the present invention without departing from the scope or spirit of the invention. For example, features illustrated or described as part of one embodiment may be used in another configuration to obtain yet another embodiment. Thus, the present invention is intended to cover those modifications and variations that are within the scope of the appended claims. When parameter ranges are provided, it is intended that each of the ends of the range are also included within the given range. A person of ordinary skill in the field in question should understand that the current discussion is only a description of exemplary embodiments, and is not intended to limit the broader aspects of the invention, the broadest aspects of which are incorporated examples of constructions. Fluid-entangled laminated blanket with projections
[60] The result of the processes and equipment described herein is the generation of a fluid-entangled laminate blanket with projections that extend outward and away from at least one intended outer surface of the laminate. In preferred embodiments, the projections are hollow. An embodiment of the present invention is shown in Figures 1, 2, 2A, 8, 9 and 9A of the drawings. A fluid-entangled laminate web 10 is shown with projections 12 which, for many applications, are desirably hollow. The mat 10 includes a backing layer 14 (which in Figures 1, 2 and 2A is shown as a non-woven fibrous backing mat 14) and a non-woven fibrous projection mat 16. The backing layer 14 has a first surface 18 and a second opposing surface 20, as well as a thickness 22. The projection mat 16 has an inner surface 24 and an opposite outer surface 26, as well as a thickness 28. The interface between the backing layer 14 and the projection mat 16 is shown by reference numeral 27 and it is desirable for the fibers of the projection mat 16 to cross the interface 27 and intertwine and wrap the backing layer 14 to form the laminate 10. When the backing layer or mat 14 is also a In a fibrous nonwoven fabric, the fibers of this layer may pass through the interface 27 and intertwine with the fibers in the projection mat 16. The overall laminate 10 is termed a fluid-entangled laminate mat, because of the fibrous nature of the projection mat 16 portion of the laminate 10, while it is understood that the backing layer 14 is referred to as the layer as it is composed of fibrous weft material, such as non-woven material, but can also be composite and include other materials such as, for example, films, foams and reinforcing fabrics. In general, for the end-use applications outlined herein, the basis weights of the fluid-entangled laminate mat 10 will range between about 25 and 100 gsm, although basis weights outside this range may be used depending on the particular end-use application. . hollow projections
[61] While the projections 12 may be filled with fibers from the projection mat 16 and/or the backing layer 14, it is generally desirable for the projections 12 to be hollow, especially when these laminates 10 are being used in connection with absorbent structures. The hollow projections 12 desirably have closed ends 13 which are devoid of holes or openings. Such holes or openings must be distinguished from the normal interstitial spacing between fibers commonly found in non-woven fibrous mats. In some applications, however, it may be desirable to increase the pressure and/or interrupt time of application of the jets of fluid in the entanglement process as described below to create one or more holes or openings (not shown) in one or more hollow projections 12. Such openings may be formed at the ends 13 or side walls 11 of the projections 12, as well as at both ends 13 and side walls 11 of the projections 12.
[62] The hollow projections 12 shown in the figures are round when viewed from above with slightly domed or curved tops or ends 13 when viewed cross-sectionally. The actual shape of the projections 12 can be varied depending on the shape of the forming surface through which the fibers of the projection mat 16 are forced. Thus, while not being limited to variations, the shapes of the projections 12 can be, for example, round, oval, square, rectangular, triangular, lozenge, etc. The width and depth of the hollow projections 12 can be varied, as can the spacing and pattern of the projections 12. In addition, different shapes, sizes and spacing of projections 12 can be used on the same projection mat 16.
[63] The projections 12 on the projection mat 10 are located on and emanate from the outer surface 26 of the projection mat 16. When the projections 12 are hollow, they will have open ends 15 which are located towards the inner surface 24 of the projection mat 16. projection 16 and are covered by the second surface 20 of the backing layer or mat 14 or the inner surface 24 of the projection mat 16, depending on the amount of fibers that have been used from the projection mat 16 to form the projections 12. The projections 12 are surrounded by landing areas 19 which are also formed from the outer surface 26 of the projection mat 16, although the thickness of the landing areas 19 is comprised of both the projection mat 16 and the support layer 14. This landing area 19 it may be relatively flat as shown in Figure 1 or it may have topographic variability built in. For example, the landing area 19 can have a plurality of three-dimensional shapes formed in the landing area by forming the projection mat 16 on a three-dimensional forming surface, as is disclosed in US Patent No. 4,741,941 to Englebert et al., assigned to Kimberly-Clark Worldwide and incorporated herein by reference in its entirety for all purposes. For example, the landing areas 19 may be provided with depressions 23 that extend all or part of the way into the projection mat 16 and/or the support layer 14. In addition, the landing areas 19 may be subjected to to the embossing, which can impart surface texture and other functional attributes to the landing area 19. Still further, the landing areas 19 and the laminate 10 as a whole may be equipped with openings 25 that extend through the laminate 10 in order to further facilitate the circulation of fluids (such as the liquids and solids that form body exudates) in and through the laminate 10. As a result of the fluid entanglement processes described herein, it is generally not desirable for the pressure of the fluid used to form the projections 12 has sufficient force to force the fibers of the backing layer 14 to be exposed on the outer surface 26 of the projection mat 16.
[64] While it is possible to vary the density and fiber content of the projections 12, it is generally desirable for the projections 12 to be “hollow”. Referring to Figures 9 and 9A, it can be seen that when the projections 12 are hollow, they tend to form an envelope 17 from the fibers of the projection mat 16. The envelope 17 defines an interior hollow space 21 that has a density less fiber compared to the density of the housing 17 of the projections 12. By “density” is meant the number of fibers or the content per unit volume chosen in a part of the interior hollow space 21 or the housing 17 of the projection 12. The thickness of the shell 17, as well as its density, may vary within a particular projection 12 or may also vary between different projections 12. Furthermore, the size of the hollow interior space 21, as well as its density, may vary within a particular projection 12 and may also vary between different projections 12. The photomicrographs of Figures 9 and 9A reveal a lower density or fiber count in the interior hollow space 21 compared to the housing portion 17 of the projection 12 illustrated. As a result, if there is at least a part of an interior hollow space 21 of a projection 12 that has a lower fiber density than at least a part of the shell 17 of the same projection 12, then the projection is considered to be "hollow". ”. In this regard, in some situations, there may not be a well-defined boundary between the housing 17 and the interior hollow space 21, but if there is sufficient enlargement of a cross-section of one of the projections, it is possible to see that at least a part of the The inner hollow space 21 of the projection 12 has a lower density than a part of the housing 17 of the same projection 12, so the projection 12 is considered to be "hollow". Furthermore, if at least a portion of the projections 12 of a fluid-entangled laminate mat 10 are hollow, the projection mat 16 and laminate 10 are considered "hollow" or "having hollow projections." Typically, the portion of the projections 12 that are hollow will be greater than or equal to 50 percent of the projections 12 in a chosen area of the fluid-entangled laminated mat 10, alternatively, greater than or equal to 70 percent of the projections in a chosen area of the fluid-entangled laminated mat 10 and, alternatively, greater than or equal to 90 percent of the projections 10 in a chosen area of the fluid-entangled laminated mat 10.
[65] As will become more evident in connection with the description of the processes set forth below, the fluid-entangled laminated mat 10 is the result of the movement of fibers in the projection mat 16 in one or sometimes two or more directions. With reference to Figures 2A and 3A, whenever the projection forming surface 130 on which the projection mat 16 is placed is solid, except for the forming apertures 134 used to form the hollow projections 12, then the force of the entanglement fluid flows hitting and rebounding from the solid surface area 136 of the projection forming surface 130 corresponding to landing areas 19 of the projection mat 16 can cause a migration of fibers adjacent to the interior surface 24 of the projection mat 16 in the support layer 14 adjacent its second surface 20. This fiber migration in the first direction is represented by the arrows 30 shown in Figure 2A. To form the hollow projections 12, which extend outward from the outer surface 26 of the projection mat 16, there must be a migration of fibers in a second direction, as shown by arrows 32. It is this migration in the second direction that causes projection mat fibers 16 move outward and away from outer surface 26 to form hollow projections 12.
[66] When the backing layer 14 is a non-woven fibrous mat, depending on the degree of mat integrity and the strength and time of interruption of the entanglement fluid from the jets of fluid under pressure, there may also be movement of the fibers of the mat. support mat into projection mat 16 as shown by arrows 31 in Figure 2A. The net result of these fiber movements is the creation of a laminate 10, with good overall integrity, and the lamination of the layer and mat (14 and 16) at their interfaces 27, thereby allowing further processing and handling of the laminate 10. Support layer and projection blanket
[67] As the name implies, the support layer 14 is intended to support the projection mat 16 which contains the projections 12. The support layer 14 can be made of any number of structures as long as the support layer 14 is capable of to support the projection mat 16. The primary functions of the support layer 14 are to protect the projection mat 16, during formation of the projections 12, to be able to attach to or be entangled with the projection mat 16 and assist in further processing of the projection mat 16 and the resulting fluid-entangled laminate mat 10. Suitable materials for the backing layer 14 may include, but are not limited to, non-woven mats or fabrics, reinforcing fabric materials, netting materials, products based on paper/cellulose/wood pulp that may be considered a subset of non-woven fabrics or blankets, as well as foam materials, films and combinations of the above, provided that the material or materials chosen are capable of withstanding the fluid entanglement process. A particularly suitable material for the backing layer 14 is a non-woven fibrous batt made from a plurality of randomly deposited fibers, which may be staple fibers such as those used, for example, in carded batts, air-processed batts, etc. , or they may be continuous fibers such as those found in, for example, meltblown or spunbond blankets. Due to the functions that the support layer 14 must perform, the support layer 14 must have a higher degree of integrity than the projection mat 16. In this regard, the support layer 14 must be able to remain substantially intact when subjected to the fluid entanglement process discussed in more detail below. The degree of integrity of the backing layer 14 must be such that the material forming the backing layer 14 resists being drawn down and filling the hollow projections 14 of the projection mat 16. As a result, when the backing layer 14 is a non-woven fibrous batt, it is desirable for it to have a higher interfiber bonding and/or fiber entanglement than the fibers of the projection batt 16. While it is desirable for the fibers of the backing layer 14 to entangle with the fibers of the projection mat 16 adjacent to the interface 27 between the two layers, it is generally desirable that the fibers of this backing layer 14 are not integrated or entangled in the projection mat 16 such that large parts of these fibers find their way into the hollow projections 12 .
[68] The function of the support layer 14 is to further facilitate the processing of the projection mat 16. Typically, the fibers used to form the projection mat 16 are more expensive than those used to form the support layer 14. As a result , it is desirable to keep the basis weight of the projection mat 16 low. In doing so, however, it becomes difficult to process the projection mat 16 subsequent to its formation. By attaching the projection mat 16 to an underlying support layer 14, further processing, winding and unwinding, storage and other activities can be done more efficiently.
[69] To resist this higher degree of fiber movement, as mentioned above, it is desirable for the backing layer 14 to have a higher degree of integrity than the projection mat 16. This higher degree of integrity can be achieved in countless ways. One is fiber-to-fiber bonding, which can be achieved through thermal or ultrasonic bonding of the fibers to each other, with or without the use of pressure, as in air processing bonding, spot bonding, powder bonding, chemical bonding. , adhesive bonding, embossing, calender adhesion, etc. In addition, other materials can be added to the fibrous mixture, such as adhesives and/or bicomponent fibers. The pre-entanglement of the fibrous non-woven backing layer 14 can also be used, for example, by subjecting the web to hydroentanglement, needle-punching, etc. before this mat 14 is connected to the projection mat 16. Combinations of the above are also possible. Still other materials such as foams, reinforcing fabrics and nets may have sufficient initial integrity to require additional processing. The level of integrity can, in many cases, be visually observed due to, for example, naked eye observation of such techniques as stitch binding, which is commonly used with non-woven fibrous blankets such as spunbond blankets and fiber-containing blankets. discontinuous. Further enlargement of the backing layer 14 may also reveal the use of entanglement fluid or the use of thermal bonding and/or adhesive to bond the fibers together. Depending on the availability of samples from the individual layers (14 and 16), machine direction or cross-machine tensile tests can be performed to compare the integrity of the support layer 14 with that of the projection mat 16. See for example , the ASTM D5035-11 test, which is incorporated herein in its entirety for all purposes.
[70] The type, basis weight, strength and other properties of the backing layer 14 can be selected and varied depending on the particular end use of the resulting laminate 10. When the laminate 10 is to be used as part of an absorbent article, as a absorbent toiletries, handkerchief, etc., it is generally desirable that the backing layer 14 be a fluid permeable layer, have good wet and dry resistance, be able to absorb fluids such as body exudates, possibly retain fluids for a certain period of time and then release them and one or more underlying layers. In this regard, non-woven fibrous batts such as spunbond, meltblown, carded, airflow formed, carded and bonded and co-formed batts are particularly well suited as backing layers 14. Foam materials and reinforcing fabric materials are also well suited. . In addition, the backing layer 14 can be a multi-layer material, due to the use of multiple layers or the use of multi-bank forming processes, such as are commonly used in the manufacture of spunbond and meltblown mats, as well as mat layer combinations. meltblown and spunbond. In forming such support layers 14, natural and synthetic materials can be used singly or in combination to manufacture the material. In general, for the end-use applications outlined herein, the basis weights of the backing layer 14 will range between about 5 and 40 gsm, although basis weights outside this range may be used depending on the particular end-use application.
[71] The type, basis weight and porosity of the support layer 14 will affect the process conditions required to form the projections 12 on the projection mat 16. Heavier basis weight materials will increase the entanglement force of the flows than the fluid flows. entanglement need to form projections 12 on projection mat 16. However, heavier basis weight support layers 14 will also provide better support for projection mat 16, as one of the major problems with projection mat 16 alone is that it is too elastic to maintain the shape of the projections 12 after the forming process. The projection mat 16, by itself, elongates unduly in the machine direction due to the mechanical forces exerted on it by subsequent converting and winding processes, which diminish and distort the projections 12. Furthermore, without the support layer 14, the projections 12 on the projection mat 16 collapses due to the winding pressures and compression pressures that the projection mat 16 experiences in the winding process and subsequent conversion and does not recover as they do in the presence of the support layer 14.
[72] The backing layer 14 can be subjected to post-treatment and/or additives to change or improve its properties. For example, surfactants and other chemicals can be added either internally or externally to the components that form all or part of the backing layer 14 to change or improve its properties. Compounds commonly called hydrogels or superabsorbents which absorb many times their weight in liquid can be added to the support layer 14 in the form of particles and fibers.
[73] The projection batt 16 is made from a plurality of randomly deposited fibers which may be staple fibers such as those used, for example, in carded batts, airflow processed batts, coformed batts, etc., or they can be made of more continuous fibers, such as meltblown or spunbond blankets. The fibers in the projection batt 16 desirably should have less interfiber bonding and/or fiber entanglement and thus less integrity compared to the integrity of the backing layer 14, especially when the backing layer 14 is a non-fibrous batt. woven. The fibers in the projection mat 16 may be devoid of inter-fiber bonding to allow the formation of hollow projections 12, as will be explained in more detail below in connection with the description of one or more of the embodiments of the process and equipment for forming the mat. fluid-entangled laminate 10. Alternatively, when both the backing layer 14 and the projection mat 16 are both fibrous non-woven webs, the projection mat 16 will have less integrity than the backing layer 14 due to the projection mat 16 that has, for example, less bonding between fibers, less adhesive or less pre-entanglement of the fibers that form the mat 16.
[74] The projection web 16 must have a sufficient amount of fiber movement capability to allow the fluid entanglement process described below to be able to move the fibers of the projection web 16 out of the XY plane of the web. projection 16 as shown in Figure 1 and in the perpendicular direction or in the Z direction (its thickness direction 28) of the blanket 16 to form the hollow projections 12. If more blanket structures are being used, such as meltblown blankets or spunbond, it is desirable to have little or no pre-gluing of the projection mat 16 prior to the fluid entanglement process. Longer fibers, such as those generated in meltblowing and spunbonding processes (which are often called continuous fibers to differentiate them from longitudinally bonded fibers) typically require more force to displace the fibers. in the Z direction than shorter fibers, which generally have fiber lengths less than 100 millimeters (mm) and more typically fiber lengths between 10 and 60 mm. On the other hand, staple fiber batts, such as carded or airflow processed batts, may have some degree of pre-bonding or fiber entanglement due to their shorter length. Such shorter fibers require less force from the entanglement fluid flows to move them in the Z direction to form the hollow projections 12. As a result, a balance has to be struck between fiber length, fiber preglue degree, fluid force, blanket velocity and dwell time, so as to create hollow projections 12 without, unless desired, forming perforations in landing areas 19, hollow projections 12, or forcing material too much into space hollow interior 21 of the projections 12, making them 12 too rigid for some end-use applications.
[75] Generally, the projection mat 16 will have a basis weight ranging between about 10 and 60 gsm for the uses described herein, however, basis weights outside this range may be used depending on the specific end-use application. Spunbond mats will generally have a basis weight of between about 15 and 50 grams per square meter (gsm) when used as a projection mat 16. Fiber diameters will vary between about 5 and 20 microns. The fibers may be single component fibers formed from a single polymeric composition, or they may be two or more component fibers, where a portion of the fiber has a lower melting point than the other components to allow the bonding between fibers through the use of heat and/or pressure. Hollow fibers can also be used. The fibers can be formed from any polymer formulations typically used to form spunbond mats. Examples of such polymers include, but are not limited to, polypropylene (PP), polyester (PET), polyamide (PA), polyethylene (PE) and polylactic acid (PLA). Spunbond mats can be subjected to post-form bonding and entanglement techniques to improve mat processability prior to subjecting it to the projection forming process.
[76] Meltblown mats will generally have a basis weight of between about 20 and 50 grams per square meter (gsm) when used as a spray mat 16. Fiber diameters will vary between about 0.5 and 5 microns. The fibers may be single component fibers formed from a single polymeric composition, or they may be two or more component fibers, where a portion of the fiber has a lower melting point than the other components to allow the bonding between fibers through the use of heat and/or pressure. The fibers may be formed from any of the polymer formulations typically used to form the aforementioned spunbond mats. Examples of such polymers include, but are not limited to, PP, PET, PA, PE and PLA.
[77] Carded and airflow processed mats use staple fibers that will generally range in length between about 10 and 100 millimeters. The denier count of the fibers will vary between about 0.5 and 6 denier count, depending on the particular end use. Basis weights will range between about 20 and 60gsm. Staple fibers can be made from a variety of polymers, including, but not limited to, PP, PET, PA, PLA, cotton, linen, rayon, wool, hemp and regenerated cellulose such as, for example, viscose. Fiber blends may also be used, such as blends of two-component fibers and single-component fibers, as well as blends of solid fibers and hollow fibers. If bonding is desired, it can be done in a variety of ways, including, for example, by airflow bonding, calender bonding, spot bonding, chemical bonding, and adhesive bonding such as powder bonding. If necessary, to further improve the integrity and processability of such webs prior to the projection forming process, they may be subjected to pre-entanglement processes to increase entanglement of the fibers within the projection web 16, prior to forming. 12. Hydroentanglement is particularly advantageous in this respect.
[78] While the aforementioned types of non-woven mats and forming processes are suitable for use in conjunction with the projection mat 16, it is anticipated that other mat forming processes may also be used, provided the mats are capable of to form the hollow projections 12. Process description
[79] To form the materials according to the present invention, a fluid entanglement process must be employed. Any number of fluids can be used to bond the backing layer 14 and the projection mat 16 including liquids and gases. The most common technology used for this is known as spunlace or hydroentanglement technology, which uses water as the pressurized fluid for entanglement.
[80] Returning to Figure 3 of the drawings, there is shown a first embodiment of a process and apparatus 100 for forming a fluid-entangled laminate web 10 with hollow projections 12 in accordance with the present invention. Equipment 100 includes a first conveyor belt 110, a conveyor belt drive roller 120, a projection forming surface 130, a fluid entanglement device 140, an optional overfeed roller 150, and a fluid removal system 160. , such as a vacuum device or other conventional suction device. Such vacuum devices and other means are well known to people of common knowledge. The conveyor belt 110 is used to transport the projection mat 16 within the equipment 100. If any pre-entanglement is to be done on the projection mat 16 upstream of the process shown in Figure 3, the conveyor belt 110 can be porous. The conveyor belt 110 moves in a first direction (which is in the machine direction) as shown by the arrow 112 at a first speed or speed V 1. The conveyor belt 110 can be driven by the conveyor belt drive roll 120 or other suitable means as are well known to persons of common knowledge.
[81] The projection forming surface 130, as shown in Figure 3, is in the form of a texturing cylinder 130, a partially exploded view of the surface which is shown in Figure 3A. The projection forming surface 130 moves in the machine direction, as shown by the arrow 131 in Figure 3 at a speed V3. It is driven and its speed controlled by any suitable driving means (not shown), such as electric motors and gears, are well known to persons of ordinary skill. The texturing cylinder 130 shown in Figures 3 and 3A consists of a forming surface 132 that contains forming holes 134 that correspond to the shape and pattern of the desired projections 12 on the projection mat 16. The forming holes 134 are separated by an area landing holes 136. Formation holes 134 can be of any shape or pattern. As can be seen from the figures depicting the laminates 10 in accordance with the present invention, the hole shapes are round, but it should be understood that any number of shapes and combination of shapes may be used depending on the end-use application. Examples of possible hole shapes include, but are not limited to, ovals, squares, crosses, rectangles, hexagons, diamonds, and other polygons. Such shapes can be formed on the drum surface by casting, punching, stamping, laser cutting and waterjet cutting. The spacing of the forming holes 134 and, therefore, the degree of landing area 136 may also vary depending on the particular end-use application of the fluid-entangled laminate mat 10. In addition, the pattern of the forming holes 134 in the texturing cylinder 130 may vary. vary depending on the particular end application of the fluid-entangled laminate mat 10. The forming material of the texturing cylinder 130 can be any number of suitable materials commonly used for such forming drums, including, but not limited to, sheet metal, plastics materials. and other polymeric materials, rubber, etc. Forming holes 134 can be formed into a sheet of material 132 which is then formed into a texturing cylinder 130 or the texturing cylinder 130 can be molded or cast from appropriate materials or printed with 3D printing technology. Typically, the perforated cylinder 130 is fitted over an optional porous inner cylinder housing 138 so that different forming surfaces 132 can be used for different end product designs. The porous inner cylinder housing 138 connects to the fluid removal system 160, which facilitates pulling the entanglement fluid and fibers into the forming holes 134 in the outer surface of the texturing cylinder 132, thereby forming the hollow projections 12 of the projection mat 16. The porous inner cylinder housing 138 also acts as a barrier to retard the downward movement of the fiber into the fluid removal system 160 and other parts of the equipment, thus reducing fouling of the equipment. The porous inner cylinder shell 138 rotates in the same direction and at the same speed as the texturing cylinder 130. Furthermore, to further control the height of the projections 12, the distance between the inner cylinder housing 138 and the texturing cylinder 130 can be varied. In general, the spacing between the inner surface of the projection forming surface 130 and the outer surface of the inner cylinder housing 138 will vary between about 0 and 5 mm. Other ranges may be used depending on the particular end-use application and the desired characteristics of the fluid-entangled laminate mat 10.
[82] The depth of the forming holes 134 in the texturing cylinder 130 or other projection forming surface 130 may be from 1 to 10 mm, but preferably between about 3 mm and 5 mm to produce the projections 12 with the most useful format in the common applications expected. The cross-sectional size of the hole may be between about 2 mm and 10 mm, but is preferably between 3 mm and 6 mm, measured along the major axis, and the spacing of the forming holes 134 from center to center may be be between 3 mm and 10 mm, but preferably between 4 mm and 7 mm. The spacing pattern between the forming holes 134 can be varied and selected for the particular end use. Some examples of patterns include, but are not limited to, aligned row and/or column patterns, skew patterns, hexagonal patterns, wavy patterns, and patterns that illustrate images, data, and objects.
[83] The cross-sectional dimensions of the forming holes 134 and their depth influence the cross-section and height of the projections 12 produced in the projection mat 16. Generally, hole shapes with sharp or narrow corners on the leading edge of the forming holes 134, since machine direction 131 should be avoided as they can sometimes impair the ability to safely remove the fluid-entangled laminate mat 10 from the forming surface 132 without damaging the projections 12. In addition, the hole thickness/depth in the texturing cylinder 130 will generally tend to correspond to the depth or height of the hollow projections 12. It should be noted, however, that the hole depth, spacing, size, shape, and other parameters may be varied independently of one another and may be varied. based on the particular end use of the fluid-entangled laminate web 10 to be formed.
[84] Landing areas 136 on forming surface 132 of texturing cylinder 130 are generally solid so as not to pass entanglement fluid 142 emanating from jets of pressurized fluid contained in fluid entanglement devices 140, but in In some cases, it may be desirable to make the landing areas 136 fluid permeable to further texture the exposed surface of the projection mat 16. If preferred, selected areas of the forming surface 132 of the texturing cylinder 130 may be fluid permeabilized, while other areas remain impermeable. For example, a central region (not shown) of texturing cylinder 130 may be fluid-permeable, while lateral regions (not shown) on either side of the central region may be fluid-impervious. In addition, the landing areas 136 on the forming surface 132 may have raised areas (not shown) formed therein or attached thereto to form optional depressions 23 and/or the perforations 25 in the projection mat 16 and the fluid-tangled laminate mat. 10.
[85] In the embodiment of the equipment 100 illustrated in Figure 3, the projection forming surface 130 is shown in the form of a texturing cylinder. It should be appreciated, however, that other means may be used to create the projection forming surface 130. For example, a porous belt or cable (not shown) may be used that includes forming holes 134 formed in the belt or cable in appropriate locations. Alternatively, flexible rubber belts (not shown), which are impervious to pressurized entanglement fluid flows, except for forming holes 134, may be used. Such belts and cables are well known to persons of ordinary skill as they are means of driving and controlling the speed of such belts and cables. A texturing cylinder 130 is most advantageous for forming the fluid-entangled laminated mat 10 in accordance with the present invention as it can be made with landing areas 136 that are smooth and impervious to entanglement fluid 142 and do not leave a weave pattern of the cord on the outer surface 26 of the projection mat 16, as mesh belts tend to do.
[86] An alternative to a forming surface 132 with a hole depth that defines the height of the projection is a forming surface 132 that is thinner than the desired projection height, but which is spaced from the surface of the cylinder housing. porous inner 138 to which it is attached. The spacing between the texturing cylinder 130 and the porous inner cylinder housing 138 may be achieved by any means that preferably does not interfere with the process of forming the hollow projections 12 and removes tangling fluid from the equipment. For example, one of the means is a stiff yarn or filament that can be inserted between the texturing cylinder 130 and the porous inner cylinder housing 138 as a spacer or wrapped around the porous internal cylinder housing 138 below the texturing cylinder. 130 to provide proper spacing. A shell depth of the forming surface 132 of less than 2 mm can make it more difficult to remove the projection mat 16 and laminate 10 from the texturing cylinder 130 as the fibrous material of the projection mat 16 may expand or move with the flow. of entanglement fluid, into a protruding area beneath the texturing cylinder 130 which, in turn, can distort the fluid-entangled laminate web 10. It has been found, however, that using a backing layer 14 in together with the projection mat 16, as part of the forming process, the distortion of the resulting two-layer fluid-entangled laminate mat 10 can be greatly reduced. The use of a backing mat 14 generally facilitates the removal of cleaning liquid from the fluid-entangled laminate mat 10, as the less elastic, the more dimensionally stable the backing layer 14 can withstand the load while the fluid-entangled laminate 10 is removed from the texturing cylinder 130. The greater tension that can be applied to the backing layer 14, compared to a single projection mat 16, means that the fluid-entangled laminate 10 moves away from the texturing cylinder 130, the projections 12 can exit forming holes 134 smoothly, in a direction half perpendicular to forming surface 132 and coaxially with forming holes 134 in texturing cylinder 130. In addition, by using backing layer 14, processing speeds can be increased.
[87] To form the projections 12 on the projection mat 16 and to laminate the backing layer 14 and the projection mat 16 together, one or more fluid entanglement devices 140 are spaced above the projection forming surface 130. A The most common technology used in this context is known as spunlace or hydroentanglement technology, which uses pressurized water as the entanglement fluid. As an unbonded or relatively unbonded mat or mats are introduced into a fluid entanglement device 140, several jets of pressurized fluid (not shown) from one or more fluid entanglement devices 140 move the mat fibers and the turbulence of the fluid causes the fibers to tangle. These fluid flows (which in this case, the fluid is water) can cause the fibers to be entwined even further within the individual mats. Flows can also cause fiber movement and entanglement at the interface 27 of two or more mats/layers, causing the mats/layers to stick together. Furthermore, if the fibers in a mat, such as the projection mat 16, are loosely joined, they may move out of their XY plane, and therefore in the Z direction (see Figures 1 and 2A), to form the projections. 12 which are preferably hollow. Depending on the level of entanglement required, one or more fluid entanglement devices 140 may be used.
[88] In Figure 3 a single fluid entanglement device 140 is shown, but in the following Figures, where multiple devices 140 are used in various regions of the equipment 100, they are marked with designator letters such as 140a, 140b, 140c, 140d and 140e. When multiple devices are used, the pressure of the entanglement fluid in each subsequent device 140 is generally higher than the previous one, so that the energy transmitted to the batts/layers increases, as does the fiber entanglement of the fibers within or between the fibers. blankets/layers. This reduces the disruption of the overall uniformity of the blanket/layer area density by the pressurized fluid jets, while reaching the desired level of entanglement and, consequently, the mating of the blankets/layers and formation of the projections 12. The entanglement fluid 142 fluid entanglement devices 140 emanate from the injectors via jet packs or strips (not shown) consisting of one or more lines of pressurized fluid jets with small openings in diameter generally between 0.08 and 0.15 mm and a spacing of approximately 0.5 mm in the transverse direction of the machine. The pressure in the jets can be from approximately 5 bar to 400 bar, but is generally less than 200 bar, with the exception of heavy fluid-entangled laminate blankets and when fibrillation is required. Other jet sizes, spacings, jet numbers and jet pressures can be used depending on the particular end application. Such fluid entanglement devices 140 are well known to people of common knowledge and are readily available from manufacturers such as Fleissner of Germany and Andritz-Perfojet of France.
[89] Fluid entanglement devices 140 will typically have jet holes positioned or spaced between about 5 millimeters and about 20 millimeters, and more typically, between about 5 and about 10 millimeters from the projection forming surface 130, although the actual spacing may vary depending on the basis weights of materials being used, the pressure of the fluid, the number of individual jets being used, the amount of vacuum being used through the fluid removal system 160, and the speed at which the equipment is operating.
[90] In the embodiments shown in Figures 3 to 7, the fluid entanglement devices 140 are conventional hydroentanglement devices whose construction and operation are well known to those of ordinary skill. See, for example, US Patent No. 3,485,706 to Evans, the contents of which are incorporated herein in their entirety by reference for all purposes. See also the description of the hydroentanglement equipment described by Honeycomb Systems, Inc., Biddeford, Maine, in the article entitled “Rotary Hydraulic Entanglement of Nonwovens”, reproduced from the INSIGHT '86 INTERNATIONAL ADVANCED FORMING conference /BONDING Conference, the contents of which are incorporated herein by reference in their entirety for all purposes.
[91] Returning to Figure 3, the projection mat 16 is introduced into the equipment and process 100 at a speed V1, the backing layer 14 is introduced into the equipment and process 100 at a speed V2 and the fluid-entangled laminate mat 10 comes out. of the equipment and process 100 at a speed V3, which is the speed of the projection forming surface 130 and may also be referred to as the velocity of the projection forming surface. As will be explained in more detail below, these velocities V1, V2 and V3 can be the same or different, to alter the formation process and properties of the resulting fluid-entangled laminated mat 10. The introduction of the projection mat 16 and the layer of support 14 in the process at the same speed (V1 and V2) will produce a fluid-entangled laminate web 10 in accordance with the present invention with the desired hollow projections 12. Introducing the projection mat 16 and backing layer 14 into the process at the same speed, which is faster than the machine direction speed (V3) of the projection forming surface 130, will also form the desired hollow projections 12.
[92] Also shown in Figure 3 is an optional overfeed roller 150, which can be driven at a speed or rate Vf. The overfeed roller 150 can be rotated at the same speed as the speed V1 of the projection mat 16, in which case Vf will be equal to V1 or it can be rotated at a faster rate to tension the projection mat 16 upstream of the overfeed roller 150 when overfeed is desired. Overfeeding occurs when one or both mats/layers (16, 14) are introduced to the projection-forming surface 130 at a rate greater than the speed of the projection-forming surface 130. It has been found that improved projection formation in the projection mat 16 can be affected by feeding the projection mat 16 to the projection forming surface 130 at a rate greater than the input velocity V2 of the support layer 14. In addition, however, it has been found that the improved properties and projection formation can be achieved by varying the feed rates of the mats/layers (16, 14) and also using the overfeed roller 150, immediately upstream of the texturing cylinder 130 to feed a greater amount of fibers through the projection mat. 16 for subsequent movement by the entanglement fluid 142 into the forming holes 134 in the texturing cylinder 130. In particular, the overfeeding of the d and projection 16 into the texturing cylinder 130, better projection formation can be obtained, including increased projection height.
[93] To provide excess fiber so that the height of the projections 12 is maximized, the projection mat 16 can be fed into the texturing cylinder 130 at a greater surface speed (V1) than the speed (V3) ) of the texturing cylinder 130. Referring to Figure 3, when overfeeding is desired, the projection mat 16 is introduced into the texturing cylinder 130 at a speed V1 while the support layer 14 is introduced at a speed V2 and the texturing roller 130 travels at a speed V3 which is slower than V1 and may be equal to V2. The percentage or overfeed ratio at which the projection mat 16 is introduced into the texturing cylinder 130 can be defined as OF = [(V1 / V3) - 1]x100, where V1 is the inlet speed of the spray mat 130. projection 16 and V3 is the output speed of the resulting fluid-entangled laminated mat 10 and the speed of texturing cylinder 130. (When overfeed roller 150 is being used to speed up material entering texturing cylinder 130, it should be noted that the material speed V1 after the overfeed roll 150 will be faster than the speed V1 upstream of the overfeed roll 150. When calculating the overfeed ratio, it is this fastest speed V 1 that should be used.) Good formation of projections 12 was observed when the supercharge ratio is approximately 10 to 50 percent. It is also noted that this overfeed and ratio technique can be used with respect not only to the projection mat 16, but a combination of the projection mat 16 and backing layer 14 as they are introduced together into the forming surface. projection 130.
[94] To minimize the length of the projection mat 16 that is supporting its own weight before being subjected to entanglement fluid 142 and to prevent wrinkling and bending of the projection mat 16, the overfeed roller 150 can be used to convey the projection mat 16 at a speed V 1 to a position close to the texturing zone 144 on the texturing cylinder 130. In the example illustrated in Figure 3, the feed roller 150 is driven off the conveyor belt 110, but it is also possible to drive it separately so as not to place undue stress on the material of the projection mat 16. The support layer 14 can be introduced into the texturing zone 144 separately from the projection mat 16 and at a speed V2 which may be greater, equal to or less than the speed of the texturing cylinder V3 and greater than, equal to or less than the speed V 1 of the projection mat 16. Preferably, the support layer 14 is pulled into the zone of texturing cylinder 144 by its frictional engagement with the projection mat 16 positioned on the texturing cylinder 130 and thus, once in the texturing cylinder 130, the backing layer 14 has a surface speed close to the speed V3 of the texturing cylinder 130 or it can be positively introduced into the texturing zone 144 at a speed close to the speed V3 of the texturing cylinder. The texturing process causes some shrinkage of the support layer 14 in the machine direction 131. The overfeed of the support layer 14 or projection mat 16 can be adjusted according to the particular materials, equipment and conditions being used, accordingly. so that excess material that is introduced into the texturing zone 144 is used, thus preventing any wrinkling in the resulting fluid-entangled laminate web 10. As a result, the two webs/layers (16, 14) will be under some tension at all times. moments, despite the process of overfeeding. The peel speed of the fluid-entangled laminate mat 10 should be arranged to be close to the speed V3 of the texturing cylinder, such that excessive tension is not applied to the laminate during its removal from the texturing cylinder 130, since the excessive tension could be detrimental to the clarity and size of the projections.
[95] An alternative embodiment of the process and equipment 100 in accordance with the present invention is shown in Figure 4, in which like reference numerals are used for like elements. In this embodiment, the main differences are a pre-entanglement of the projection mat 16 to improve its integrity before further processing through a pre-entanglement with fluid 140a; a lamination of the projection mat 16 to the backing layer 14 through a fluid entanglement laminator 140b; and an increase in the number of fluid entanglement devices 140 (so-called fluid entanglement devices for projections 140c, 140d and 140e) and thus an enlargement of the texturing zone 144 in the texturing cylinder 130 in the projection forming part of the process.
[96] The projection mat 16 is supplied to the process/equipment 100 via the conveyor belt 110. As the projection mat 16 travels over the conveyor belt 110, it is subjected to a first fluid entanglement device 140a. to improve the integrity of the projection mat 16. This may be termed pre-entanglement of the projection mat 16. As a result, this conveyor belt 110 must be fluid permeable to allow the entangling fluid 142 to pass through the projection mat 110. projection 16 and conveyor belt 110. To remove applied entanglement fluid 142, as in Figure 3, a fluid removal system 160 such as a vacuum fluid removal device or other conventional device may be used below the belt conveyor. conveyor 110. The fluid pressure of the first fluid entanglement device 140a is generally in the range of approximately 10 to 50 bar.
[97] The backing layer 14 and projection mat 16 are then introduced into a lamination-forming surface 152 with the first surface 18 of the mat or backing layer 14 facing over and in contact with the lamination-forming surface 152 and the second surface 20 of the support layer 14 in contact with the inner surface 24 of the projection mat 16. (See Figures 2 and 4.) To entangle the support layer 14 and the projection mat 16 together, one or more devices Laminating Fluid Entanglements 140b are used with the Lamination Forming Surface 152 to affect fiber entanglement between materials. Again, a fluid removal system 160 is used for disposing of the entanglement fluid 142. To distinguish the equipment in this part of the process rolling and complete equipment 100 from the subsequent projection forming part, where the projections are formed, the equipment and process cited is laminating equipment as opposed to projection forming equipment. Accordingly, this part relates to the use of a lamination forming surface 152 and a fluid entanglement lamination device 140b which utilizes jets of lamination fluid as opposed to projection forming jets. The lamination forming surface 152 is movable in the machine direction of the equipment 100 at a lamination forming surface speed and must be permeable to the tangling fluid emanating from the jets of lamination fluid located in the fluid entanglement laminating device 140b . The fluid entanglement lamination device 140b has several jets of lamination fluid capable of emitting a plurality of pressurized lamination fluid streams from the entanglement fluid 142 towards the lamination forming surface 152. The lamination forming surface 152 (when in the cylinder configuration shown in Figure 4) it can have several holes that form in its surface separated by landing areas to make it permeable to fluid or it can be made of conventional forming mesh, which is also permeable. In this part of the equipment 100, the complete bonding of the two materials (14 and 16) is not necessary. The process parameters of this part of the equipment are similar to those of the projection forming part, and the description of the equipment and process in connection with Figure 3. Thus, the velocities of materials and surfaces in the roll forming part of the equipment and process can be varied, as explained above in relation to the projection forming equipment and process described in relation to Figure 3.
[98] For example, the projection mat 16 can be fed into the lamination-forming process and into the backing layer 14 at a rate greater than the rate at which backing layer 14 is introduced onto the lamination-forming surface 152. In With respect to entanglement fluid pressures, lower lamination fluid jet pressures are desired in this part of the equipment, as additional mat/layer entanglement will occur during the projection forming part of the process. As a result, the lamination forming pressures of the lamination entanglement device 140b will generally range between approximately 30 and 100 bar.
[99] When several streams of lamination fluid 142 in fluid entanglement laminating device 140b are directed towards the outer surface 26 of projection mat 16 towards lamination forming surface 152, at least a portion of the fibers in the projection mat 16 entangle with backing layer 14 to form a laminate mat 10. Once the projection mat 16 and backing layer 14 are joined into a laminate 10, the laminate 10 exits the laminating part of the equipment and process (elements 140b and 152) and is introduced in the projection forming part of the equipment and process (elements 130, 140c, 140d, 140e and 150 optional). As with the process shown in Figure 3, the laminate 10 can be fed into the projection forming surface/texturing cylinder 130 at the same speed that the texturing cylinder 130 is traveling or it can be supercharged into the texturing cylinder 130 using the overfeed roll 150 or, simply causing the laminate 10 to move at a speed V1 which is greater than the speed V3 of the projection forming surface 130. As a result, the process variables described above with respect to Figure 3 of the drawings can also be used with the equipment and process shown in Figure 4. In addition, as with the equipment and materials in Figure 3, if the overfeed roll 150 is used to increase the speed V 1 of the laminate 10 as it comes into contact with the projection forming surface 130, it is this fastest speed V1 after the overfeed roller 150 that is to be used in calculating the ratio d and overfeeding. The same approach should be used in calculating the overfeed ratio with the rest of the embodiments shown in Figures 4a, 5, 6 and 7 if material overfeed is used.
[100] In the projection forming part of the equipment, a plurality of pressurized fluid flows projecting the entanglement fluid 142 from several fluid jets located in the projecting fluid entanglement devices (140c, 140d and 140e) into the laminated mat 10 in a direction from the first surface 18 of the backing layer 14 toward the projection forming surface 130 to create a first plurality of fibers in the projection mat 16 in the vicinity of the forming holes 134 in the projection forming surface 130 to be directed into forming holes 134 and form a plurality of projections 12 projecting outward from the outer surface 26 of projection mat 16, and thereby forming the fluid-entangled laminate mat 10 in accordance with the present invention. As with other processes, the formed laminate 10 is removed from the projection forming surface 130 and, if desired, may be subjected to the same or an additional different process as described with respect to the equipment and process in Figure 3 , such as drying to dry to remove excess entanglement or additional bonding fluid or other steps. In the projection forming part of the equipment and equipment 100, the forming pressures of the projection fluid entanglement devices (140c, 140d and 140e) will generally range between about 80 and 200 bar.
[101] A further modification of the process and equipment 100 of Figure 4 is shown in Figure 4A. In Figures 4, as well as subsequent embodiments of the equipment and process shown in Figures 5 and 7, the fluid-entangled laminate mat 10 is subjected to a pre-lamination step via lamination-forming surface 152 and one or more more fluid entanglement lamination devices 140b. In each of the configurations (Figures 4, 5 and 7), the material that is in direct contact with the lamination forming surface 152 is the first surface 18 of the backing layer 14. However, it is also possible to invert the layer of support 14 and the projection mat 16, as shown in Figure 4A, such that the outer surface 26 of the projection mat 16 is the side that is in direct contact with the roll forming surface 152 and this alternative version of equipment and The process of Figures 4, 5 and 7 is also within the scope of the present invention as well as variations thereof.
[102] Another alternative embodiment of the process and equipment 100 according to the present invention is shown in Figure 5. This embodiment is similar to what is shown in Figure 4, except that only the projection mat 16 is subjected to pre-entanglement using entanglement fluid devices 140a and 140b before projection mat 16 is introduced into the projection forming part of the equipment. In addition, the backing layer 14 is introduced into the texturing zone 144 on the projection/cylinder forming surface 130 in the same manner as in Figure 3 although the texturing zone 144 is provided with multiple fluid entanglement devices (140c, 140d and 140e).
[103] Figure 6 represents another embodiment of the process and equipment according to the present invention which, like Figure 4, place the projection mat 16 and the support layer 14 in contact with each other for a treatment. in a lamination part of the equipment and process using a lamination forming surface 152 (which is the same element as the conveyor belt 110) and a lamination fluid entanglement device 140b. Furthermore, like the embodiment of Figure 4, in the texturing zone 144 the projection forming part of the process and equipment 100, multiple projection fluid entanglement devices (140c and 140d) are used.
[104] Figure 7 represents another embodiment of the process and equipment 100 in accordance with the present invention. In Figure 7, the main difference is that the projection mat 16 undergoes a first treatment with the entanglement fluid 142 through a projection fluid entanglement device 140c in the texturing zone 144 before the second surface 20 of the coating layer. support 14 is brought into contact with the interior surface 24 of the projection mat 16 for fluid entanglement through fluid entanglement device 140d. In this way, an initial formation of the projections 12 begins without the backing layer 14 being in place. As a result, it may be desirable for the projection fluid entanglement device 140c to be operated at a lower pressure than the projection fluid entanglement device 140d. For example, the projection fluid entanglement device 140c can be operated in a pressure range of 100 to about 140 bar, while the projection fluid entanglement device 140d can be operated in a pressure range of about 140 bar. from 140 to 200 bar. Other pressure combinations and ranges may be chosen depending on the operating conditions of the equipment and the types and basis weights of materials being used for the projection mat 16 and backing layer 14.
[105] In each of the embodiments of the process and equipment 100, the fibers in the projection mat 16 are sufficiently spaced and movable within the projection mat 16 so that the entanglement fluid 142 emanating from the jets of fluid from The projection in the texturing zone 144 is capable of moving a sufficient number of fibers out of the XY plane of the projection mat 16 in the vicinity of the forming hole holes 134 in the projection forming surface 130 and forcing the fibers down and in. of the forming holes 134, thus forming the hollow projections 12 of the projection mat 16 of the fluid-entangled laminated mat 10. Furthermore, by overfeeding at least part of the projection mat 16 to the texturing zone 144, the formation of improved projections can be achieved as shown in the examples and photomicrographs below. EXAMPLES
[106] To demonstrate the process, equipment and materials of the present invention, a series of fluid-entangled laminated mats 10 were made, as well as projection mats 16, without the support layers 14. Samples were made on a production line. spunlace at Textor Technologies PTY LTD in Tullamarine, Australia, similar to that shown in Figure 5 of the drawings, with the only exception being that a fluid entanglement device 140c was used to form the projections 12 in the texturing zone 144. In addition In addition, the projection mat 16 was pre-wetted upstream of the process shown in Figure 5 and before the fluid pre-entanglement device 140a using conventional equipment. In this case, pre-wetting was achieved through the use of a single injector set at a pressure of 8 bar. The fluid pre-entanglement device 140a was set at 45 bar, the fluid entanglement device 140b was set at 60 bar, while the pressure of the simple fluid entanglement device 140c was varied as shown in Tables 1 and 2 below at pressures of 140, 160 and 180 bar, depending on the particular sample being run.
[107] For conveyor belt 110 in Figure 5, fluid pre-entanglement device 140a was positioned at a height of 10 mm above conveyor belt 110. For lamination forming surface 152 entanglement lamination device with fluid 140b was positioned at a height of 12 mm above the surface 152, as was the projecting fluid entanglement device 140c with respect to the projection forming surface 130.
[108] Projection forming surface 130 was a 1.3 m wide steel texturing cylinder with a diameter of 520 mm, thickness 3 mm, and a hexagonal pattern of 4 mm round forming holes, spaced apart. by a center spacing of 6 mm. The porous inner cylinder housing 138 was a 100 mesh (100 threads per inch in both directions/39 threads per centimeter in both directions) of braided stainless steel mesh. The separation or clearance between the outside of the housing 138 and the inside of the cylinder 130 was 1.5 mm.
[109] The process parameters that were varied were the aforementioned entanglement fluid pressures (140, 160 and 180 bar) and the degree of supercharging (0%, 11%, 25% and 43%), using the supercharging ratio above-mentioned OF = [(V1 / V 3) - 1]x100 where V 1 is the input speed of the projection mat 16 and V3 is the output speed of the resulting laminate 10.
[110] All samples were run at the exit line or at takeoff speed (V3) of about 25 meters per minute (m/min). V1 is reported in Tables 1 and 2 for their samples. V2 was held constant for all samples in Tables 1 and 2 at a speed equal to V3 or 25 meters per minute. Final samples were sent through a line dryer to remove excess water, as is common in the hydroentanglement process. Samples were collected after drying and then labeled with a code (see Tables 1 and 2) to match the process conditions used.
[111] Regarding the materials made, as indicated below, some were made with a backing layer 14 and some were not, and when a backing layer 14 was used, there were three variations, including a spunbond blanket, a spunlace blanket, and a airflow bonded carded blanket (TABCW). The spunbond backing layer 14 was a 17 grams per square meter (gsm) polypropylene dot-bonded mat made from 1.8 denier grade polypropylene continuous bond fibers, which was subsequently dot-bonded with an area overall connection per unit area of 17.5%. The spunbond blanket was made by Kimberly-Clark Australia of Milsons Point, Australia. The spunbond material was supplied and fed into the process in the form of a roll, with an approximate roll width of 130 centimeters. The spunbond mat was a 52 gsm spunlace material using a uniform blend of 70 weight percent viscose staple fiber, 40 mm long, 1.5 denier strength and 30 weight percent polyester staple fiber (PET ), 38 mm long, 1.4 denier grade, manufactured by Textor Technologies PTY LTD of Tullamarine, Australia. The spunbond material was preformed and supplied in roll form, and had an approximate roll width of 140 centimeters. The TABCW had a basis weight of 40 grams and comprised a uniform blend of 40 weight percent PET staple fiber 51 mm long, 6 denier grade, and 60 weight percent polyethylene/core coated bicomponent staple fiber. polypropylene, 51 mm long, 3.8 denier grade, manufactured by Textor Technologies PTY LTD of Tullamarine, Australia. In the data below (see Table 1) under the heading “support layer”, the spunbond mat was identified as “SB”, the spunlace mat was identified as “SL” and the TABCW was identified as “S”. When no support layer 14 was used, the term “None” appears. The basis weights used in the examples should not be considered a limitation on the basis weights that can be used, as the basis weights of the support layers can be varied depending on the end applications.
[112] In all cases, the projection batt 16 was a carded staple batt made from 100% polyester staple fiber, 38 mm long, 1.2 denier, available from Huvis Corporation of Daejeon, Korea. The carded mat was manufactured in-line with the hydroentanglement process by Textor Technologies PTY LTD of Tullamarine, Australia and had a width of approximately 140 centimeters. The basis weights varied as indicated in Tables 1 and 2 and ranged between 28 gsm and 49.5 gsm, although other basis weight ranges may be used depending on the final application. Projection blanket 16 was identified as “blanket card” in the data below in Tables 1 and 2.
[113] The thickness of the materials described in Tables 1 and 2 below, as well as Figure 11 of the drawings, was measured using a Mitutoyo model IDC1025B thickness gauge with a presser pressure of 345Pa (0.05 psi). Measurements were taken at room temperature (about 20 degrees Celsius) and reported in millimeters using a round foot with a diameter of 76.2 mm (3 inches). The thicknesses of the selected samples (average of three samples) with and without support layers are shown in Figure 11 of the drawings.
[114] The tensile strength of the materials, defined as the peak load obtained during the test, was measured both in the machine direction (MD) and in the transverse machine direction (CMD), using an Instron model tensile tester. 3343 operating the Instron Series IX Rev. 1.16 software module with a +/- 1kN load cell. The initial grip separation distance (“calibration length”) was set at 75 millimeters and the loading speed was 300 millimeters per minute. The width of the claw was 75 millimeters. The samples were cut to 50mm wide by 300mm long on the MD and each tensile strength test result reported the average of two samples per code. The samples were evaluated at room temperature (about 20 degrees Celsius). Excess material was removed from the ends and sides of the equipment. CMD forces and strains were also measured, and generally, CMD forces were about one-half to one-fifth of the MD force and CMD strains at peak load were about two to three times greater than in the MD direction. (The CMD samples were cut to the long dimension on the CMD). MD forces were reported in Newtons per 50 mm material width. (Results are shown in Tables 1 and 2.) The MD lengths of material at peak load were reported as a percentage of the initial gauge length (initial grip separation).
[115] Extension measurements were also taken and reported in the MD at a load of 10 Newtons (N). (See Tables 1 and 2 below and Figure 12.) Tables 1 and 2 show data based on the variation of the support layer being used, the degree of superfeed being used, and variations in water pressure from the hydroentanglement water jets. .
[116] As an example of the consequences of different process parameters, high overfeed requires sufficient jet pressure to push the projection mat 16 into the texturing cylinder 130 and also absorb excess material being overfed in the texturing zone 144 If there is not enough jet energy available to overcome the material's resistance to texturing, then the material will bend and overlap and, in the worst case, may form a roll before the texturing zone 144 requiring the process to be stopped. Although the experiments were conducted at a V3 line speed of 25m/min, this should not be considered as a limitation for the line speed as equipment with similar materials was driven at line speeds ranging from 10 to 70 m /min and speeds outside this range may be used depending on the materials being processed.
[117] The following tables summarize materials, process parameters and test results. The samples shown in Table 1 were made with and without support layers. Codes 1.1 to 3.6 used the aforementioned spunbond backing layer. Codes 4.1 to 5.9 had no backing layer. Jet pressures for each sample are listed in the Table. Table 1: Experimental parameters and test results, with support layer and without support layer, codes 1 to 5.


[118] *Note for codes 4.1 to 5.9 the “laminate” was a single layer structure, there was no backing layer present.
[119] For Table 2, samples 6SL.1 to 6SL.6 were run on the same equipment, under the same conditions as the samples in Table 1 with the aforementioned spunlace support layer, while samples 6S.1 to 6S .4 were performed with the backing layer of the carded mat bonded to air. The projection blankets (“card blankets”) were manufactured in the same way as those used in Table 1. Table 2. Experimental parameters and test results code 6, with alternative support layers.

[120] As can be seen from Tables 1 and 2, the key quality parameter of fabric thickness, which is a measure of the height of the projections, as indicated by the thickness values, depended primarily on the amount of projection blanket overfeed 16 in the texturing zone 144. In relation to the data presented in Table 2, it is possible to see that high overfeed ratios resulted in an increase in thickness. Furthermore, at the same supercharge ratios, higher fluid pressures resulted in higher thickness values which in turn indicate an increase in projection height. Table 2 shows the test results for samples made with alternative support layers. The 6S codes used a 40 gsm airflow bonded carded blanket and the 6SL codes used a 52 gsm spunlace material. These samples performed well and had good stability and appearance when compared to unsupported and unsupported samples.
[121] Figure 11 of the drawings represents the sample thickness in millimeters in relation to the percentage of overfed projection mat for a laminate (represented by a diamond) versus two samples that did not have a backing layer (represented by a square and a triangle). All reported values were an average of three samples. As can be seen from the data in Figure 11, as the overfeed increased, the sample thickness also increased, showing the importance and advantage of using overfeed.
[122] Figure 12 of the drawings is a graph representing the percentage of sample extension at a load of 10 Newton in relation to the amount of supercharged projection mat for the materials in Table 1. As can be seen in the graph of Figure 12 , when the backing layer was not present, there was a drastic increase in the machine direction extensibility of the resulting sample as the percentage of material overfeed in the texturing zone increased. In contrast, the sample with the spunbond backing layer experienced virtually no increase in percentage extension consonant with increasing overfeed ratio. This in turn resulted in the projection blanket having projections that are more stable during subsequent processing and that are better able to maintain their shape and height.
[123] As can be seen from the graph data, higher supercharging, and hence, higher draw height, also decreased MD tensile strength and increased MD extension at peak load. This is because the increased texturing provided more material (in the projections) that did not immediately contribute to the tensile strength and load generation and allowed for greater extension before peak load was reached.
[124] One of the main benefits of laminated both projection mat and backing layer compared to single layer and no backing layer spray mat is that the backing layer can reduce the excessive extension during subsequent processing and converting that can remove the texture of the fabric and reduce the height of the projections. Without the integration of the support layer 14 to the projection formation process, it was very difficult to form the mats with the projections that can continue to be processed without the forces and stresses of the process acting on the mat and negatively affecting the integrity of the projections, especially when low base weight blankets are desired. Other means can be used to stabilize the material, such as thermal bonding or adhesive or increased entanglement, but these means tend to lead to a loss of softness and greater stiffness, as well as increased costs. The fluid-entangled laminate mat of the present invention can provide both softness and stability simultaneously. The difference between supported and unsupported textured materials is clearly illustrated in the last column of Table 1 which, for comparison, shows the extent of the samples at a load of 10N. The data are also shown in Figure 12 of the drawings. It is possible to see that the sample supported by the spunbond support layer stretched only a small percentage at an applied load of 10 Newtons (N) and was almost independent of the overfeed. In contrast, the unsupported projection blanket stretched by up to 30% at a load of 10 Newton; the extension at 10N was heavily dependent on the overfeed used to texturize the sample. Low extensions at 10N can be achieved by unsupported mats, but only with low superfeed, which results in low projection height, ie, little mat texturing.
[125] Figure 13 of the drawings shows an example of the load-strain curves obtained in the tensile test of samples in the machine direction (MD), which is the direction in which higher loads are most likely to be experienced in dissolution. and the material under further processing and conversion. The examples shown in Figure 13 were all made using an overfeed ratio of 43% overfeed and had approximately the same areal density (45 gsm). It can be seen that the sample containing the spunbond support layer had a much higher initial modulus, the beginning of the curve was sharp compared to that of the unsupported single projection blanket blanket by itself. This initial steeper part of the curve for the sample with the backing layer was also recoverable, as the sample was elastic up to the point where the gradient began to decrease. The unsupported sample had a very low modulus, permanent deformation, and texture loss at a lower load. Figure 13 of the drawings shows the load-strain curves for both supported and unsupported tissue. Note the relative slope of the initial part of the curve for the supported fabric/laminate in accordance with the present invention. This means that the unsupported sample is relatively easily stretched and a high extent is required to generate any tension in it compared to the supported sample. Tension is often required for stability in further processing and conversion, but the unsupported sample is more likely to experience permanent deformation and loss of texture as a result of the high strain required to maintain tension.
[126] Figures 14 and 15 of the drawings show a set of curves for a wide range of conditions. You can see that the samples with a low level of texturing from the low superpower were stiffer and stronger (although they were a little lighter), but the lack of texture made them useless in this context. All samples of laminates supported in accordance with the present invention had higher initial gradients compared to unsupported ones.
[127] The level of improvement in the overall quality of the fluid-entangled laminated mat 10 when compared to a projection mat 16 without a backing layer 14 cannot be seen by comparing the photographs of the materials shown in Figures 16, 16A, 17, 17A and 18. Figures 16 and 16A are photos of the sample represented by Code 3-6 in Table 1. Figures 17 and 17A are photos of the sample represented by Code 5-3 in Table 1. These codes were selected as they both had the highest amount of superfeed (43%) and jet pressure (180 bar) using comparable spray mat basis weights (38 gsm and 38.5 gsm respectively) and therefore the highest potential for good formation of projection. As can be seen by comparing the two codes and attached photos, the supported mat/laminate formed much more robust and visually perceptible projections and uniform material than the same projection mat without a backing layer. They also had better properties, as shown by the data in Table 1. As a result, the supported laminate according to the present invention is much better suited for further processing and use in such products as, for example, absorbent toiletries.
[128] Figure 18 is a photograph at the interface of a projection blanket with and without a support layer. As can be seen in this photograph, the supported projection blanket has a much higher level of integrity. This is especially important when the material will be used in end-use applications such as absorbent personal care articles, where it is necessary (often with the use of adhesives) to attach the projection mat to underlying layers of the product. With the unsupported projection mat, adhesive leakage is a much greater threat. Such leakage can result in clogging of processing equipment and undesired adhesion of the layers, thereby causing excessive downtime with equipment manufacturing. In use, the unsupported projection mat is more likely to allow fluids absorbed by the absorbent article (such as blood, urine, faeces and menses) to flow back or “de-wet” the top surface of the material, thus resulting in a product bottom.
[129] Another obvious advantage of visually observing the samples (not shown) was the coverage and degree of flatness of the backside of the first surface 18 on the outside of the backing layer 14 and thus the laminate 10 resulting from the forming process. , compared to the inner surface 24 of a projection mat 16 performed by the same process 100 without a backing layer 14. Without the backing layer 14, the outer surface of the projection mat 16 opposite the projections 12 was irregular and relatively uneven. to soar. In contrast, the same outer surface of the fluid-entangled laminate mat 10 in accordance with the present invention with the backing layer 14 was smoother and much flatter. As long as such flat surfaces improve the laminate's ability to adhere to other materials for later conversion. As seen in the exemplary embodiments of the products described below, when fluid-entangled laminate mats 10 in accordance with the present invention are used in items such as absorbent personal care articles having flat surfaces that readily interface with adjacent layers, it is important in the context of joining the laminate to other surfaces in order to allow the rapid passage of fluids through the various layers of the product. If good surface-to-surface contact between layers is not present, fluid transfer between adjacent layers can be compromised. Product realization forms
[130] Fluid-entangled laminate blankets in accordance with the present invention have a wide variety of possible end-uses, especially where adsorption, transfer and fluid detachment are important. Two particularly hard non-limiting areas of use involve food packaging and other absorbent articles, such as absorbent personal care articles, bandages and the like. In food packaging, it is desirable to use absorbent pads within food product packages to absorb fluids emanating from packaged products. This is particularly true for meat and seafood products. The bulky nature of the materials provided herein is beneficial in that the projections can help keep packaged products away from the released fluids residing at the bottom of the package. In addition, the laminate may be coupled to a liquid impermeable material, such as a film layer on the first side 18 of the backing layer 14 via adhesives or other means, so that fluids entering the laminate will be contained therein.
[131] Absorbent personal care items include products such as diapers, pantyhose, training pants, adult incontinence products, feminine hygiene products, wet and dry wipes, bandages, absorbent breastfeeding pads, bed liners, change liners diapers and the like. Feminine hygiene products include sanitary pads, night pads, panty liners, tampons and the like. When such products are used to absorb bodily fluids such as blood, urine, menstrual flow, feces, drainage fluids from wounds and surgical sites, etc., generally desired attributes of such products include fluid absorption capacity, softness, resistance and separation of the affected part of the body to promote a drier sensation and facilitate the flow of air for comfort and well-being of the skin. Laminates in accordance with the present invention can be designed to provide such attributes. The hollow projections promote fluid transfer and separation from the rest of the laminate. As a lighter, softer material can be chosen for skin contact, which in turn is supported by a stronger support material, softness can also be imparted. In addition, because of the void volume created by the landing areas around the projections, the area is designed to allow for the collection of unabsorbed solid materials. This void volume, in turn, can be useful when product is removed as the combination of projections and void areas allow the laminate to be used in cleaning mode to clean soiled skin surfaces. These same benefits can also be realized when the laminate is used as either a wet or dry wipe, which makes laminate desirable for products such as baby and adult wet and dry wipes, household cleaning wipes, bath and beauty wipes, for cosmetic purposes and applicators, etc. Furthermore, in any or all of these applications, the laminate 10 and in particular the landing areas 19 may be perforated to further facilitate fluid flow.
[132] Personal care absorbent articles or simply absorbent articles generally have certain key components that the laminate of the present invention can use. Returning to Figure 10, an absorbent article 200 is shown which in this case is a basic disposable diaper model. Generally, such products 200 will include a body side liner or skin contacting material 202, a garment side material, also called a backsheet or baffle 204, and an absorbent core 206 disposed between the body side liner. 202 and backsheet 204. In addition, it is also very common for the product to have an optional layer 208, commonly called a peak or transfer layer, disposed between the body side liner 202 and the absorbent core 206. Other layers and components may also be incorporated into products as they will be readily appreciated by those skilled in the art in such product formation.
[133] The fluid-entangled laminated mat 10 in accordance with the present invention may be used as a whole or part of one or all of these aforementioned components of such personal care products 200, including one of the outer surfaces (202 or 204). ). For example, laminate mat 10 can be used as a liner for body side 202 if it is more desirable for projections 12 to face outward so as to be in a body-contacting position on product 200. Laminate 10 can be also be used as a peak or transfer layer 208 or as the absorbent core 206 or a part of the absorbent core 206. Finally, from a softness and aesthetic point of view, the laminate 10 can be used as the outermost side of the sheet. 204, in which case it may be desirable to attach a liquid impermeable film or other material to the first side 18 of the backing layer 14.
[134] Laminate 10 can also be used to serve various functions within an absorbent personal care article 200, as shown in Figure 10. For example, projection mat 16 can act as a liner on the side of the body 202. and the backing layer 14 can act as the peaking layer 208. In this regard, the materials in the examples with the "S" backing layers are particularly advantageous in providing such functions. See Tables 1 and 2.
[135] When such products are in the form of diapers and adult incontinence devices, they may also include what are termed "ears" located in the front and/or back waist regions on the sides of the products. These ears are used to fix the product on the user's torso, usually in conjunction with adhesive and/or mechanical hook and loop fastening systems. In certain applications, the fastening systems are connected to the distal ends of the ears and connected to what is called a “front patch” or “tape landing zone”, located at the front of the product's waist. The fluid woven laminate web of the present invention may be used for all or part of any one or more of these components and products.
[136] When such absorbent articles are in the form of a training diaper, diaper pants, incontinence pants or other products that are designed to be worn as underwear, such products will generally include so-called “side panels”, joining the from the front and back waist of the product. Such side panels may include both elastic and non-elastic portions, and the fluid-entangled laminate batts of the present invention may be used with all or part of such side panels.
[137] Accordingly, such absorbent articles may have at least one layer, in whole or in part, comprising the fluid-entangled laminated mat of the present invention.
[138] These and other modifications and variations to the present invention may be made by persons of ordinary skill in the art, without departing from the spirit and scope of the present invention, which is defined in more detail in the appended claims. Furthermore, it is to be understood that aspects of the various embodiments may be interchanged in whole or in part. Furthermore, persons of ordinary skill in the art will appreciate that the above description is for the purpose of exemplification only, and should not be interpreted as a limitation of the invention, described in more detail in the appended claims.

权利要求:
Claims (6)
[0001]
1. A method of forming a fluid-entangled laminate web having projections comprising: providing a projection-forming surface (130) that defines a plurality of forming holes (134), such forming holes (134) being spaced apart from one another. the other and having landing areas (136) therebetween, said projection forming surfaces (130) being capable of moving in a machine direction at a projection forming surface velocity (V3), providing a landing device fluid entanglement (140) having a plurality of projecting fluid jets capable of emitting a plurality of projecting pressurized entanglement fluid streams (142) from said plurality of projecting fluid jets towards said forming surface projection mat (130), providing a support layer (14), said support layer (14) having a first opposing surface and a second surface, providing a projection mat (14) non-woven fabric (16) composed of fibers, where the projection mat (16) has an opposite inner surface and an outer surface, introducing the projection mat (16) over the projection forming surface (130) with the outer surface of the projection mat (16) positioned adjacent the projection forming surface (130), introducing the second surface of the support layer (14) onto the interior surface of the projection mat (16), directing the plurality of fluid flows from pressurized projection of the entanglement fluid (142) from the plurality of fluid jets in a direction from the first surface of the support layer (14) towards the projection forming surface (130) to cause a) the first plurality of fibers in the projection mat (16) around the forming holes (134) in the projection forming surface (130) are directed into the forming holes (134) to form a plurality of projections (12) extending outward from the outer surface of the projection mat (16), and b) a second plurality of fibers in the projection mat (16) entangle with the backing layer (14) to form a laminate mat (10, and remove the laminated mat (10) of the projection forming surface (130), characterized in that the projection mat (16) which is introduced into the projection forming surface (130) at a speed (V1) greater than the speed (V2) of the support layer (14) is introduced into the projection mat (16), or at the same speed as the support layer (14) which is faster than the projection forming surface speed (V3) .
[0002]
2. Process according to claim 1, characterized in that the projection mat (16) is introduced into the projection forming surface (130) at a superfeed ratio between 10 and 50 percent.
[0003]
3. A process for forming a fluid-entangled laminate web (10) having hollow projections (12) comprising: providing a lamination-forming surface (152) that is permeable to fluids, where the lamination-forming surface (152) is capable of moving in the machine direction at a lamination forming surface speed, providing a projection forming surface (130) defining a plurality of forming holes (134), such forming holes (134) being spaced from each other and having landing areas (136) therebetween, these projection forming surfaces (130) being capable of moving in a machine direction at a projection forming surface speed (V3), provide a fluid entanglement lamination device (140b) having a plurality of jets of lamination fluid capable of emitting a plurality of pressurized streams of lamination fluids of an entanglement fluid (142) from a laminator. flows of lamination fluid towards the lamination forming surface (152), providing a fluid entanglement device (140) having a plurality of jets of projection fluid capable of emitting a plurality of streams of pressurized projection fluid from a entanglement fluid (142) from projecting fluid jets towards said projection forming surface (130), providing a support layer (14), said support layer (14) having a first opposing surface and a second surface, providing a non-woven projection mat (16) composed of fibers, wherein the projection mat (16) has an opposite inner surface and an outer surface, introducing said backing layer (14) and said projection (16), on said lamination forming surface (152), directing the plurality of pressurized lamination fluid streams from the plurality of lamination fluid jets into the sud layer. (14) and projection mat (16) to cause at least a portion of said projection mat (16) fibers to entangle with said backing layer (14) to form a laminate mat (14) 10), introducing the laminated mat (10) onto the projection forming surface (130) with the outer surface of the projection mat (16) adjacent to the projection forming surface (130), directing the plurality of fluid flows from pressurized projection of the entanglement fluid from the plurality of jets of projection fluid on the laminated mat (10) in a direction from the first surface of the support layer (14) towards the projection-forming surface (130) to make whereby a first plurality of fibers in the projection mat (16) around the forming holes (134) in the projection forming surface (130) are directed into the forming holes (134) to form a plurality of projections (134). 12) that extend away from the outer surface of the projection mat (16), and removing the laminate mat (10) from the projection forming surface (130); wherein the backing layer (14) is introduced into the lamination-forming surface (130) with the first surface adjacent to the lamination-forming surface (152), that inner surface of the projection mat (16) is introduced into the second surface of the support layer (14), and the plurality of streams of pressurized lamination fluid are directed from the plurality of jets of lamination fluid in a direction from the outer surface of the projection mat (16) towards the surface of lamination forming (152) to cause at least part of the fibers of the projection mat (16) to become entangled with the backing layer (14) to form a laminated mat (10); characterized in that the projection mat (16) is introduced into the backing layer (14) at a speed that is greater than a speed that the backing layer (14) is introduced into the lamination forming surface (130).
[0004]
4. Process according to claim 1 or 3, characterized in that the projection forming surface (130) comprises a texturing cylinder.
[0005]
5. Process according to claim 4, characterized in that said landing areas (136) of said projection forming surface (130) are not permeable to entanglement fluid.
[0006]
6. Process according to claim 1 or 3, characterized in that the direction of the plurality of flows of pressurized projection fluid causes the formation of projections (12), which are hollow.

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同族专利:

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公开号 | 公开日

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KR101654496B1|2016-09-05|

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NZ708476A|2017-04-28|

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AU2013340407B2|2016-12-15|

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MX2015005335A|2015-07-14|

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EP2914766B1|2017-09-27|

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US20140121626A1|2014-05-01|

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MX341237B|2016-08-09|

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US9327473B2|2016-05-03|

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EP3282045B1|2019-03-27|

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EP2914766A1|2015-09-09|

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KR20150081305A|2015-07-13|

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EP3282045A1|2018-02-14|

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EP2914766A4|2016-08-17|

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AU2013340407A1|2015-06-11|

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IL238450D0|2015-06-30|

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WO2014068492A1|2014-05-08|

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CN104769173B|2017-04-26|

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BR112015009434A2|2017-07-04|

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RU2603611C1|2016-11-27|

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CN104769173A|2015-07-08|

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法律状态:
2018-03-06| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2018-03-13| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2018-03-20| B06I| Publication of requirement cancelled [chapter 6.9 patent gazette]|Free format text: ANULADA A PUBLICACAO CODIGO 6.6.1 NA RPI NO 2462 DE 13/03/2018 POR TER SIDO INDEVIDA. |

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2021-07-20| B06A| Patent application procedure suspended [chapter 6.1 patent gazette]|

---

2021-11-16| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2022-01-04| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 30/10/2013, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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申请号 | 申请日 | 专利标题

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US13/664,921|2012-10-31|

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